Studies on natural p-terphenyls: total syntheses of vialinin A and terrestrin B.
نویسندگان
چکیده
A powerful inhibitor of TNF-alpha production, vialinin A, was synthesized from sesamol through a series of reactions involving double Suzuki-Miyaura coupling, 2,3-dichloro-5,6-dicyano-1,4-benzoquino (DDQ) mediated de-methoxymethylation and oxidative removal of methylene acetal by lead tetraacetate. The synthetic method also made it possible to prepare a related compound, terrestrin B.
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عنوان ژورنال:
- Bioscience, biotechnology, and biochemistry
دوره 74 1 شماره
صفحات -
تاریخ انتشار 2010